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Chiral π-Conjugated Double Helical Aminyl Diradical with the Triplet Ground State

https://doi.org/10.1021/jacs.4c02057

Guo, Haoxin ; Lovell, Joshua B. ; Shu, Chan ; Pink, Maren ; Morton, Martha ; Rajca, Suchada ; Rajca, Andrzej ( April 2024 , Journal of the American Chemical Society)

Free, publicly-accessible full text available April 3, 2025
From Stable Radicals to Thermally Robust High-Spin Diradicals and Triradicals

https://doi.org/10.1021/acs.chemrev.3c00406

Shu, Chan ; Yang, Zhimin ; Rajca, Andrzej ( October 2023 , Chemical Reviews)

Free, publicly-accessible full text available October 25, 2024
Cucurbit[7]uril Enhances Distance Measurements of Spin-Labeled Proteins

https://doi.org/10.1021/jacs.3c09184

Yang, Zhimin ; Stein, Richard A. ; Pink, Maren ; Madzelan, Peter ; Ngendahimana, Thacien ; Rajca, Suchada ; Wilson, Mark A. ; Eaton, Sandra S. ; Eaton, Gareth R. ; Mchaourab, Hassane S. ; et al ( November 2023 , Journal of the American Chemical Society)

Free, publicly-accessible full text available November 29, 2024
Aromatic C–C Bond Cleavage in a Curved π-System of Aminocorannulene

https://doi.org/10.1021/acs.orglett.3c01107

Guo, Weijie ; Ding, Wanjian ; Yao, Yuqing ; Rajca, Suchada ; Li, Qiaolian ; Jiang, Hua ; Rajca, Andrzej ; Wang, Ying ( June 2023 , Organic Letters)

Free, publicly-accessible full text available June 2, 2024
Thermally Ultrarobust S = 1/2 Tetrazolinyl Radicals: Synthesis, Electronic Structure, Magnetism, and Nanoneedle Assemblies on Silicon Surface

https://doi.org/10.1021/jacs.3c03402

Yang, Zhimin ; Pink, Maren ; Nowik-Boltyk, Ewa Malgorzata ; Lu, Shutian ; Junghoefer, Tobias ; Rajca, Suchada ; Stoll, Stefan ; Casu, Maria Benedetta ; Rajca, Andrzej ( June 2023 , Journal of the American Chemical Society)

Free, publicly-accessible full text available June 21, 2024
Ultrafast Bioorthogonal Spin-Labeling and Distance Measurements in Mammalian Cells Using Small, Genetically Encoded Tetrazine Amino Acids

https://doi.org/10.1021/jacs.3c00967

Jana, Subhashis ; Evans, Eric G. ; Jang, Hyo Sang ; Zhang, Shuyang ; Zhang, Hui ; Rajca, Andrzej ; Gordon, Sharona E. ; Zagotta, William N. ; Stoll, Stefan ; Mehl, Ryan A. ( July 2023 , Journal of the American Chemical Society)

Free, publicly-accessible full text available July 12, 2024
High-Spin S = 3/2 Ground-State Aminyl Triradicals: Toward High-Spin Oligo-Aza Nanographenes

https://doi.org/10.1021/jacs.2c09241

Zhang, Hui ; Pink, Maren ; Wang, Ying ; Rajca, Suchada ; Rajca, Andrzej ( October 2022 , Journal of the American Chemical Society)

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From radical to triradical thin film processes: the Blatter radical derivatives

https://doi.org/10.1039/D1TC01541A

Calzolari, Arrigo ; Rajca, Andrzej ; Casu, Maria Benedetta ( August 2021 , Journal of Materials Chemistry C)

We demonstrate the possibility to evaporate Blatter radical derivatives in a controlled environment obtaining thin films that preserve the (poly)radical magnetic character. However, their thermal evaporation is challenging. We analyse the evaporation process and the thin film formation using thermodynamic concepts and describe the material properties also using first principles calculations. The presence of more than one radical site makes the radical more reactive, narrowing the windows left for evaporation, thus, favouring the assembly of molecules and island formation rather than two-dimensional growth.
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High-Spin ( S = 1) Blatter-Based Diradical with Robust Stability and Electrical Conductivity

https://doi.org/10.1021/jacs.2c01141

Zhang, Shuyang ; Pink, Maren ; Junghoefer, Tobias ; Zhao, Wenchao ; Hsu, Sheng-Ning ; Rajca, Suchada ; Calzolari, Arrigo ; Boudouris, Bryan W. ; Casu, Maria Benedetta ; Rajca, Andrzej ( April 2022 , Journal of the American Chemical Society)

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Bis-Spiro-Oxetane and Bis-Spiro-Tetrahydrofuran Pyrroline Nitroxide Radicals: Synthesis and Electron Spin Relaxation Studies

https://doi.org/10.1021/acs.joc.1c01670

Huang, Shengdian ; Pink, Maren ; Ngendahimana, Thacien ; Rajca, Suchada ; Eaton, Gareth R. ; Eaton, Sandra S. ; Rajca, Andrzej ( October 2021 , The Journal of Organic Chemistry)

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